Avaliação da Isomerização de α-Pineno Epóxido a Aldeído Campolênico Usando um Catalisador Obtido de Cascas de Laranja (Citrus sinensis)

• Aída Luz Villa Grupo de Investigación de catálisis ambiental, Departamento de Ingeniería Química, Universidad de Antioquia, Medellín, Antioquia, Colombia https://orcid.org/0000-0002-3770-3223
• Marta Mediavilla Facultad de Ingeniería, Universidad Central de Venezuela, UCV, P.O. Box 48.057, Caracas 1041-A, Venezuela https://orcid.org/0000-0001-9010-9795

DOI: https://doi.org/10.22209/rt.v46a03

Palavras-chave: carvão, DRX, mesoporos, resíduo, terpenos

Resumo

Cascas de Laranja (Citrus sinensis) são abundantes resíduos lignocelulósicos que podem ser utilizados como fonte de carbono para obtenção de sólidos com potencial catalítico na transformação de terpenos e seus óxidos em produtos de valor agregado. Esta pesquisa buscou avaliar a isomerização do óxido de α-pineno a aldeído canfolénico, utilizando um catalisador obtido a partir de cascas de laranja. O material OAC-Zn foi obtido pela ativação das cascas com ZnSO₄.7H₂O, seguida de tratamento térmico a 500 °C; um sólido também foi obtido a partir da pirólise da casca a 500 °C (OC-500). Através do DRX foi identificada a presença de ZnO e ZnS no OAC-Zn; As análises de TGA indicaram estabilidade térmica em OAC-Zn e OC-500; As imagens de SEM mostraram superfícies porosas de morfologia diferente, bem como a presença de microporosidade em OC-500 e mesoporosidade em OAC-Zn, que foram confirmadas por adsorção física de nitrogênio. Nas análises de EDX, os elementos C, O, Zn e S foram identificados em OAC-Zn; os resultados do TPD-NH₃ mostraram que os sólidos continham acidez média e fraca. Aldeído canfolénico foi sintetizado com uma seletividade de 96 % em um material carbonáceo mesoporoso, a partir de cascas de laranja usando ZnSO₄.7H₂O como agente ativador

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